The amount of oxygen in magmas affects their physical and chemical properties, and ultimately their impact on chemical cycles linking planetary oceans and atmospheres to their deepest interiors. A key archive of information on oxygen in magmas is the abundance of Fe2+, reduced iron, compared with Fe3+, oxidised iron. The abundance of these two forms of Fe evolves as magmas are stored in the Earth’s crust, meaning that the primary Fe2+/Fe3+ that magmas have when they enter the crust from the mantle will not be preserved at the point a magma comes to erupt.
An important information source for getting back at the chemical state of primitive magmas, before their crustal evolution, is in melt inclusions — small pockets of melt trapped as crystals grow. However, in this study we show that even these archives of early magma history are susceptible to chemical resetting. Firstly, in magma chambers at high temperature diffusion can occur, resetting all the melt inclusions to record the same activity of oxygen in the magma (oxygen fugacity). Secondly, even after eruption, as the magma is flowing along the surface of the Earth, changes in the oxygen fugacity of the surrounding magma can propagate through to the melt inclusions changing theirFe2+/Fe3+ ratio.
These results mean that to reconstruct the oxygen fugacity of primitive magma we have to 1) select our samples very carefully, and 2) characterise the crustal and eruptive processes that could have reset the melt inclusions.
Online [publisher]: https://doi.org/10.1016/j.epsl.2017.09.029
Reference: Margaret Hartley, Oliver Shorttle, John Maclennan, Yves Moussallam, Marie Edmonds. Olivine-hosted melt inclusions as an archive of redox heterogeneity in magmatic systems. Earth and Planetary Science Letters (2017).